Abstract: | The solid‐state structure of the title compound, [Na2Mn2(C32H56N2OSi2)2O2] or [1,8‐C10H6(NSiiPr3)2Mn(μ3‐O)Na(THF)]2, which lies across a crystallographic twofold axis, exhibits a central [Mn2O2Na2]4+ core, with two oxide groups, each triply bridging between the two MnIII ions and an Na+ ion. Additional coordination is provided to each MnIII centre by a 1,8‐C10H6(NSiiPr3)2 [1,8‐bis(triisopropylsilylamido)naphthalene] ligand and to the Na+ centres by a tetrahydrofuran molecule. The presence of an additional Na...H—C agostic interaction potentially contributes to the distortion around the bridging oxide group. |