Solvothermal Synthesis,Crystal Structures,and Magnetic Properties of Two Organically Templated Iron Sulfates with Chain Structures |
| |
| Authors: | Ling Ma Dan Liu Yan Xing Xianchun Liu Gaijuan Li |
| |
| Abstract: | Two new one‐dimensional (1D) organically templated iron(III) sulfates C2NH8]3 Fe3(μ3‐O)2(SO4)4] ( 1 ) and C2N2H10]C2NH7]0.5FeF(SO4)2] ( 2 ) were synthesized under solvothermal conditions and characterized by single‐crystal X‐ray diffraction, powder X‐ray diffraction (XRD), FT‐IR spectroscopy, elemental analyses, ICP analyses, and thermogravimetric analyses. Single‐crystal structure analysis reveals that both compounds show linear‐chain structures, involving FeO6 (FeF2O4) octahedra and SO4 tetrahedra. The magnetic properties of the two compounds have also been investigated. |
| |
| Keywords: | Iron Sulfates Chain structures Solvothermal synthesis X‐ray diffraction |
|
|
