Determination of the crystal structure and the spectroscopic data of Pd(N,N′ -dicyclopentyldithiooxamide)2 |
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Authors: | Hendrik C Hofmans Herman O Desseyn Roger A Dommisse Paul Van Nuffel Abe T H Lenstra |
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Institution: | (1) Laboratory of Inorganic Chemistry, University of Antwerp (R.U.C.A.), Groenenborgerlaan, 171, B-2020 Antwerp, Belgium;(2) Department of Chemistry, University of Antwerp (U.I.A.), Universiteitsplein, 1, B-2610 Wilrijk, Belgium |
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Abstract: | Summary The title compound exhibits a PdS4 coordination geometry, demonstrated by crystallographic and n.m.r. measurements. The bond distances and valence angles of the complex are discussed using the information provided by i.r. measurements. Despite the strong S,S steric hindrance in the compound, the C-C bond distance is shorter in the complex than in the free ligand. The i.r. spectra also provide evidence for strong intramolecular hydrogen bonds. |
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