Bonding in a borylene complex investigated by photoionization and dissociative photoionization |
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| Authors: | Fischer Kathrin H Schneider Michael Fischer Ingo Pfaffinger Bernd Braunschweig Holger Sztáray Bálint Bodi Andras |
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| Affiliation: | Institute of Physical and Theoretical Chemistry, University of Würzburg, Am Hubland, 97074 Würzburg, Germany. |
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| Abstract: | The borylene complex [(OC)(5)Cr=B=N(SiMe(3))(2)] has been investigated by using threshold photoelectron-photoion coincidence spectroscopy with synchrotron radiation. The ionization energy of the parent complex and the 0?K appearance energies of the sequential CO loss channels have been determined. The derived bond-dissociation energies are used to discuss bonding and energetics in this compound. |
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