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Shedding light on hidden reaction pathways in radical polymerization by a porous coordination network
Authors:Inokuma Yasuhide  Nishiguchi Satoshi  Ikemoto Koki  Fujita Makoto
Institution:Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Abstract:A coordination network comprising 2-vinyltriphenylene was treated with AIBN at a high temperature, but the radical polymerization of the vinyl monomer was completely suppressed by spatial separation and otherwise hidden aerobic oxidation pathways are enhanced.
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