Shedding light on hidden reaction pathways in radical polymerization by a porous coordination network |
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Authors: | Inokuma Yasuhide Nishiguchi Satoshi Ikemoto Koki Fujita Makoto |
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Institution: | Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan. |
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Abstract: | A coordination network comprising 2-vinyltriphenylene was treated with AIBN at a high temperature, but the radical polymerization of the vinyl monomer was completely suppressed by spatial separation and otherwise hidden aerobic oxidation pathways are enhanced. |
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