| 四元混配配合物[Ce(CH2=C(CH3)-COO)2(NO3)(phen)]2的合成、表征及晶体结构 |
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| 引用本文： | 赵曙辉,咸春颖.四元混配配合物[Ce(CH2=C(CH3)-COO)2(NO3)(phen)]2的合成、表征及晶体结构[J].无机化学学报,2002,18(6):639-642. |
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| 作者姓名： | 赵曙辉 咸春颖 |
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| 作者单位： | 东华大学化学与化工学院,上海,200051 |
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| 基金项目： | 上海市青年基金资助项目(No.2000QN34)。 |
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| 摘 要： | A new complex with mixed-quadriligand Ce(CH2=C(CH3)-COO)2(NO3)(phen)]2 has been synthesized in aqueous solution of slight acidity and characterized by elementary analysis, IR and TGA. The crystal structure determination shows that the complex belongs to triclinic, space group P1, a=9.614?, b=10.047?, c=11.821?, Z=2, α=100.88(3)°, β=106.29(3)°, γ=97.93(2)°, V=1054(5)?3, Dc=1.741g·cm-3, F(000)=546.00, μ(MoKα)=22.06cm-1. And the crystal is consisted of a binuclear molecule. The coordina-tion of Ce3+ is nine.
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| 关 键 词： | 铈 α-甲基丙烯酸 1 10-邻菲咯啉 四元配合物 晶体结构 |
| 修稿时间： | 2001年11月19 |
Synthesis, Characterization and Crystal Structure of Mixed Quadriligand Complex [Ce(CH2=C(CH3)-COO)2(NO3)(phen)]2 |
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| ZHAO Shu-Hui and XIAN Chun-Ying.Synthesis, Characterization and Crystal Structure of Mixed Quadriligand Complex [Ce(CH2=C(CH3)-COO)2(NO3)(phen)]2[J].Chinese Journal of Inorganic Chemistry,2002,18(6):639-642. |
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| Authors: | ZHAO Shu-Hui and XIAN Chun-Ying |
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| Institution: | College of Chemistry and Chemical Engineering,Donghua University, Shanghai 200051 and College of Chemistry and Chemical Engineering,Donghua University, Shanghai 200051 |
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