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Broadening of triplet-triplet absorption band in molecular structures with different spatial dimensionalities
Authors:N. I. Grigorchuk
Abstract:Within the framework of a dipole approximation, the form of the light absorption band for exciton transitions between triplet zones in one-, two-, and three-dimensional periodic molecular structures is calculated. Allowance is made for exciton attenuation as a frequency-independent parameter. The analytical expressions obtained make it possible to analyze the band for molecular structures of different spatial dimensionalities as a function of the difference in bandwidths, attenuation, and lattice temperature. Institute of the Surface Chemistry, National Academy of Sciences of Ukraine, 31, Nauka Ave., Kiev 252022, Ukraine. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 5, pp. 586–590, September–October, 1997.
Keywords:molecular structure  absorption spectrum  band form  bandwidth  attenuation  temperature
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