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Organocatalytic enantioselective substitution of MBH carbonates by 2-fluoromalonates |
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| Authors: | Bing Wang,Xavier Companyó Jing Li,Albert MoyanoRamon Rios |
| Affiliation: | a State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 30007, PR China b Department de Química Orgànica, Universitat de Barcelona, Martí i Franqués, 1-11 08028 Barcelona, Spain c Catalan Institution for Research and Advanced Studies (ICREA), Passeig Lluís Companys 23, 08018 Barcelona, Spain |
| Abstract: | The enantioselective fluoromalonate addition to Morita-Baylis-Hillman carbonates is presented. The reaction is simply catalyzed by β-isocupreidine affording the final fluorinated products in good yields and enantioselectivities. |
| Keywords: | Organocatalysis MBH carbonates Lewis base Fluorine Enantioselective |
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