Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex |
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| Authors: | Furutachi Hideki Hashimoto Koji Nagatomo Shigenori Endo Taichi Fujinami Shuhei Watanabe Yoshihito Kitagawa Teizo Suzuki Masatatsu |
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| Institution: | Department of Chemistry, Faculty of Science, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. |
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| Abstract: | A mononuclear iron(III) complex containing a peroxocarbonate ligand, Fe(qn)2(O2C(O)O)]- (qn = quinaldinate), underwent the reversible O-O bond cleavage and reformation of the peroxo group via the formation of FeIV=O or FeV=O species, which was confirmed by the resonance Raman and ESI-TOF/MS measurements. |
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