| 双(基环戊二烯基)钛(锆)聚酯、聚醚、聚胺、聚醚酯的界面合成及其热稳定性的研究 |
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| 引用本文： | 沈宏康,魏荣宝,梁娅,林琳,薛其峰.双(基环戊二烯基)钛(锆)聚酯、聚醚、聚胺、聚醚酯的界面合成及其热稳定性的研究[J].天津理工大学学报,1989(1). |
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| 作者姓名： | 沈宏康 魏荣宝 梁娅 林琳 薛其峰 |
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| 作者单位： | 天津理工学院化学工程系，天津理工学院化学工程系，天津理工学院化学工程系，天津理工学院化学工程系，天津理工学院化学工程系 |
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| 摘 要： | 在高速揽拌下,利用双(烯基环戊二烯基)二氯化钛(锆)与有机二元酸,二元酚,二元胺及羟基酸的界面缩聚,合成了新的钛(锆)聚酯、聚醚、聚胺、聚醚酯高聚物共80个。对新合成的化合物进行了IR.(?)n 等方面的测试,详细地研究了茂环上取代基的烯基对热稳定性能的影响.
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| 关 键 词： | 界面缩聚 双(烯基环戊二烯基)二氯化钛(锆) 聚醚 聚脂 聚醚脂 聚胺 TG/DTG |
INTERFACIAL SYNTHESIS OF BIS(ALKENYLCYCLOPENTADIENYL)TITANIUM/ZICONIUM POLYESTERS,POLYETHERS,POLYAMINES,POLYETHER-ESTERS |
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| Shen Hongkang Wei Rongbao Liang Ya Lin Lin Xue Qifeng.INTERFACIAL SYNTHESIS OF BIS(ALKENYLCYCLOPENTADIENYL)TITANIUM/ZICONIUM POLYESTERS,POLYETHERS,POLYAMINES,POLYETHER-ESTERS[J].Journal of Tianjin University of Technology,1989(1). |
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| Authors: | Shen Hongkang Wei Rongbao Liang Ya Lin Lin Xue Qifeng |
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| Institution: | Shen Hongkang Wei Rongbao Liang Ya Lin Lin Xue Qifeng |
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| Abstract: | Under ultra high-speed stirring,bis(alkenyl-cyclopentadienyl)titanium/zirconium dichlorides were interfacially poly-condensed with diacids,diphenols.diamines and hydroxy-acids,to give 80 new polymers,namely titanium/zirconium polyesters, polyethers,polyamines and polyether-csters.For the newly synthesized polymers,IR,Mn determinations were made,and the effects of substituted alkenyl groups on the heat stabili- ties were studied in detail. |
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