| 含碳硼烷金属有机化学研究进展 |
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| 引用本文： | 古林莎·果依其巴依,张 锐,燕 红. 含碳硼烷金属有机化学研究进展[J]. 无机化学学报, 2010, 26(5): 733-743 |
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| 作者姓名： | 古林莎·果依其巴依 张 锐 燕 红 |
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| 作者单位： | 1. 南京大学化学化工学院,配位化学国家重点实验室,南京,210093;新疆伊犁师范学院化学与生物科学学院,伊犁,835000
2. 南京大学化学化工学院,配位化学国家重点实验室,南京,210093 |
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| 摘 要： | 碳硼烷因其独特的性质,及其在应用方面的广阔前景,受到化学家们的广泛关注。本文将从结构、合成、机理、催化,以及生物活性等方面概述含碳硼烷的金属有机化学的部分最新进展。着重论述了与16e金属碳硼烷相关的反应、机理及产物。
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| 关 键 词： | 碳硼烷； 金属有机化合物； 机理； 催化； 炔烃 |
Recent Development on Organometallic Chemistry Containing Carborane Ligand |
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| GULINSA Guoyiqibayi,ZHANG Rui and YAN Hong. Recent Development on Organometallic Chemistry Containing Carborane Ligand[J]. Chinese Journal of Inorganic Chemistry, 2010, 26(5): 733-743 |
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| Authors: | GULINSA Guoyiqibayi ZHANG Rui YAN Hong |
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| Affiliation: | State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineening, Nanjing University, Nanjing 210093; College of Chemistry and Life Science, Ili Normal University, Ili, Xinjiang 835000,State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineening, Nanjing University, Nanjing 210093 and State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineening, Nanjing University, Nanjing 210093 |
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| Abstract: | Carborane has special properties and potential applications, so many chemists are interested in this field. In this perspective, the recent progress on organometallic chemistry containing carborane ligand has been briefly described, depending on the aspects of structures, synthesis, mechanism, catalysis and biological activity, focusing on the reactivity, mechanism and products of 16e metal-carborane complexes. |
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| Keywords: | carborane organometallic complex mechanism catalysis alkyne |
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