| 二正丁基锡对氨基苯乙酸酯配合物{[n-Bu2Sn(O2CCH2C6H4NH2-p)]2O}2的合成、结构及量子化学研究 |
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| 引用本文： | 张复兴,王剑秋,邝代治,冯泳兰,许志锋,陈志敏,曾荣英. 二正丁基锡对氨基苯乙酸酯配合物{[n-Bu2Sn(O2CCH2C6H4NH2-p)]2O}2的合成、结构及量子化学研究[J]. 无机化学学报, 2009, 25(2): 213-217 |
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| 作者姓名： | 张复兴 王剑秋 邝代治 冯泳兰 许志锋 陈志敏 曾荣英 |
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| 作者单位： | 衡阳师范学院化学与材料科学系,衡阳,421008 |
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| 基金项目： | 湖南省科技计划项目，湖南省教育厅重点项目，湖南省重点学科基金和湖南省重点实验室基金 |
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| 摘 要： | 二正丁基氧化锡和对氨基苯乙酸按1:1反应,合成了二正丁基锡对氨基苯乙酸酯配合物{[n-Bu2Sn(O2CCH2C6H4NH2-p)]2O}2.经X-射线衍射方法测定了其晶体结构,结构属单斜晶系,空间群P21/n.配合物是以Sn2O2构成的平面四元环为中心环的二聚体结构,锡原子均为五配位的畸变三角双锥构型.对其结构进行量子化学从头计算,探讨了配合物的稳定性、分子轨道能量以及一些前沿分子轨道的组成特征.
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| 关 键 词： | 二正丁基锡 对氨基苯乙酸 合成 晶体结构 从头计算 |
Synthesis and Crystal Structure of Dialkyltin p-aminophenylacetate Compound {[n-Bu2Sn(O2CCH2C6H4NH2-p)]2O}2 |
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| ZHANG Fu-Xing,WANG Jian-Qiu,KUANG Dai-Zhi,FENG Yong-Lan,XU Zhi-Feng,CHEN Zhi-Min and ZENG Rong-Ying. Synthesis and Crystal Structure of Dialkyltin p-aminophenylacetate Compound {[n-Bu2Sn(O2CCH2C6H4NH2-p)]2O}2[J]. Chinese Journal of Inorganic Chemistry, 2009, 25(2): 213-217 |
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| Authors: | ZHANG Fu-Xing WANG Jian-Qiu KUANG Dai-Zhi FENG Yong-Lan XU Zhi-Feng CHEN Zhi-Min ZENG Rong-Ying |
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| Affiliation: | Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Human 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Human 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Human 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Human 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Human 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Human 421008 and Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Human 421008 |
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| Abstract: | |
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| Keywords: | dialkyltin p-aminophenylacetic acid synthesis crystal structure ab initio method |
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