| 拉浆铅膏的形成机理与表征 |
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| 引用本文： | 高军,史鹏飞.拉浆铅膏的形成机理与表征[J].湖南科技大学学报(自然科学版),2005,20(2):87-91. |
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| 作者姓名： | 高军 史鹏飞 |
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| 作者单位： | 哈尔滨工业大学,应用化学系,黑龙江,哈尔滨,150001 |
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| 摘 要： | 介绍了拉浆铅膏的制备方法，并将其应用于卷式铅酸蓄电池的制作．实验电池正极活性物质利用率0．5℃放电时达到54％以上，5℃电流放电时可达38％．采用X射线衍射光谱、红外光谱、循环伏安、扫描电镜等实验与分析测试手段，对拉浆铅膏的反应机理进行了研究与表征．结果表明，由于加入粘合剂拉浆铅膏与传统铅膏反应机理有所不同，但粘合剂基本不会影响电池的充放电性能．拉浆铅膏的和膏过程其主体反应是一个物理变化过程．图7，表1，参8．
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| 关 键 词： | 铅酸蓄电池 铅膏 拉浆 粘合剂 正极活性物质 |
| 文章编号： | 1672-9102(2005)02-0087-05 |
| 修稿时间： | 2004年11月24 |
Formation mechanism and characterization of slurry lead paste |
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| GAO Jun,SHI Peng-fei.Formation mechanism and characterization of slurry lead paste[J].Journal of Hunan University of Science & Technology(Natural Science Editon),2005,20(2):87-91. |
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| Authors: | GAO Jun SHI Peng-fei |
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| Abstract: | The preparation of slurry lead paste for spirally wound lead acid batteries was presented.The utilization of positive active materials could reach 54% and 38% for 0.5C and 5C discharges respectively.Reaction mechanism of paste-mixing was investigated by means of XRD, SEM,IR and CV.Results indicate that formation mechanism of slurry lead paste is different from that of traditional lead paste,which results from the addition of binders.However,no obvious effects of binders on charge-discharge performance of lead acid batteries.The principal reaction of slurry paste-mixing is a physical process.7figs.,1tab.,8refs. |
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| Keywords: | lead acid battery lead paste slurry binders positive active material(PAM) |
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