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Sensing ammonia with ferrocene-based polymer coated tapered optical fibers
Authors:Mehdi Shadaram  Juan Martinez  Fernando Garcia  David Tavares
Affiliation:1. Department of Electrical &2. Computer Engineering , University of Texas at El Paso , El Paso, Texas, USA;3. Department of Chemistry , University of Texas at El Paso , El Paso, Texas, USA
Abstract:Abstract

The application of ferrocene-based polymers as variable index materials is discussed. The refractive index of thin film of a particular polymer known as poly(methylphenylsilyeneferrocenylene) is examined during exposure to ammonia, nitrous oxide, nitric oxide, nitrogen, carbon dioxide, carbon monoxide, and argon. A maximum of 9% deviation in the refractive index of the polymer upon exposure to ammonia is observed. The theory of operation and fabrication of polymer-coated tapered optical fiber gas sensors are explained. Experimental data is presented showing qualitative response to ammonia and other gases.
Keywords:Fiber optic gas sensors  tapered optical fibers  variable index materials
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