The Preparation and Reactions of Cationic Ruthenium(II) Complexes Containing 1,5-Cyclooctadiene and Acetonitrile |
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Authors: | T.V. Ashworth Eric Singleton |
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Affiliation: | National Chemical Research Laboratory, Council for Scientific and Industrial Research, Pretoria, 0001 Republic of South Africa |
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Abstract: | The polymer [(C8H12)RuCl2]x, (C8H12 1,5-cyclooctadiene, x > 2), dissolves in refluxing acetonitrile to form [(C8H12)RuCl(CH3CN)3]+ and, on treatment with AgPF6, [(C8H12)Ru(CH3CN)4]2+; some reactions of these cations are described. |
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Keywords: | Author to whom correspondence should be addressed |
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