Complexes of organometallic compounds : XXXIX. synthesis,infrared and mössbauer studies on monoorganotin(IV) complexes with tridentate ligands |
| |
| Authors: | L. Pellerito R. Cefalú A. Silvestri F. Di Blanca R. Barbieri H.-J. Haupt H. Preut F. Huber |
| |
| Affiliation: | Instituto di Chimica Generale, Università di Palermo, 90123 Palermo Italy;Lehrstuhl für Anorganische Chemie, Universität Dortmund, 46 Dortmund Germany |
| |
| Abstract: | Novel complexes RClSntrid, where R is Me, Ph, n-Oct, and trid2? are dianions of tridentate “planar” ligands with ONO and SNO donor atoms, were synthesized and investigated in the solid state by infrared and Mössbauer spectroscopy. Possible configurations are discussed; polymeric trigonal bipyramidal structures seem to occur, although five-coordinated monomers as well as octahedral dimers (via oxygen or sulfur bridges) are not excluded. |
| |
| Keywords: | To whom correspondence should be addressed. |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
