Novel trinuclear palladium(0) complexes; tris(tribenzylideneacetylacetone) tripalladium(solvent) complexes and their reactions |
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| Authors: | Y Ishii S Hasegawa S Kimura K Itoh |
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| Institution: | Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University, Chikusa, Nagoya 464 Japan |
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| Abstract: | In an extension of our studies on palladium(0)dibenzylideneacetone complexes, novel trinuclear palladium complexes with three molecules of tribenzylideneacetylacetone have been obtained and identified by elemental and spectroscopic analyses (IR, UV and NMR).Ligand exchange reactions, oxidative addition reactions and complex formation reaction with maleic anhydride, dimethyl acetylenedicarboxylate and para-quinones were investigated. These were found to be similar to those of palladium (0)dibenzylideneacetone complexes. |
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