Fluorine-containing carbocations. IV. The use of salt solutions of stable polyfluorinated α,α-difluorobenzyl and α-fluorodiphenylmethyl cations in antimony pentafluoride in the synthesis of polyfluorinated benzoic acids,benzophenones and diphenyldifluoromethanes |
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Authors: | YuV Pozdnyakovich VD Shteingarts |
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Institution: | Institute of Organic Chemistry, Siberian Division of the Academy of Science, 90 Novosibirsk U.S.S.R. |
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Abstract: | Polyfluorinated benzoic acids have been prepared by the hydrolysis of solutions of salts of polyfluorinated α,α-difluorobenzyl cations in SbF5. Polyfluorinated benzophenones and diphenyldifluoromethanes have been obtained both by hydrolysis and by pouring into HF solutions of the salts of polyfluorinated α-fluorodiphenylmethyl cations. |
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