Isocyanide complexes of molybdenum nitrosyl |
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Authors: | WG Kita JA McCleverty B Patel J Williams |
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Institution: | Chemistry Department, The University, Sheffield. S3 7HF Great Britain |
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Abstract: | Reaction of π-cyclopentadienylmolybdenum nitrosyl halide with CNR (R = alkyl) gives (π-C5H5)Mo(NO)X2(CNR)] (X = Br or I), Mo(NO)(CNR)5]X (X = I or PF6) and Mo(NO)(CNR)4I]; treatment of Mo(NO)(CNR)5]I with R′NH2 gives Mo(NO)(CNR)4 {C(NHR)(NHR′)}]I or Mo(NO)(CNR)4(NH2R′)]I (R′ = alkyl) depending on temperature. |
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Keywords: | Author to whom correspondence should be addressed |
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