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Isocyanide complexes of molybdenum nitrosyl
Authors:WG Kita  JA McCleverty  B Patel  J Williams
Institution:Chemistry Department, The University, Sheffield. S3 7HF Great Britain
Abstract:Reaction of π-cyclopentadienylmolybdenum nitrosyl halide with CNR (R = alkyl) gives (π-C5H5)Mo(NO)X2(CNR)] (X = Br or I), Mo(NO)(CNR)5]X (X = I or PF6) and Mo(NO)(CNR)4I]; treatment of Mo(NO)(CNR)5]I with R′NH2 gives Mo(NO)(CNR)4 {C(NHR)(NHR′)}]I or Mo(NO)(CNR)4(NH2R′)]I (R′ = alkyl) depending on temperature.
Keywords:Author to whom correspondence should be addressed  
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