Stannoboroxanes : III. Synthesis and reactions of 1,3-bis(boryloxy)tetraalkyldistannoxanes and related compounds

1,3-Bis(boryloxy)tetraalkyldistannoxanes,

, R = Me, Bu; G = CMe₂CH₂CHMe—, —CMe₂ —CMe₂ — and —CHMe—CH₂ — have been prepared from dialkyltin oxide and pyroborate, or directly from dialkyltin oxide, boric acid and glycol. A dimeric structure for these compounds is proposed on the basis of molecular weight, IR and PMR studies. The reactivity of the SnOB bond towards PhNCO and Me₃SiCl has been demonstrated.