Reactions of platnum(O) and palladium(0) complexes involving insertions into carbon—carbon bonds of electro-negatively-substituted cyclopropanes |
| |
| Authors: | M Lenarda R Ros M Graziani U Belluco |
| |
| Institution: | Istituto di Chimica Inorganica, Facoltà di Chimica Industriale, University “Ca'' Foscari”, Venexia Italy |
| |
| Abstract: | 1,1,2,2-Tetracyanocyclopropane and its 3-alkyl derivatives react with Pt0 and Pd0 complexes of the type Pt(PPh3)2(C2H4) or MLn (n = 3,4; M = Pd or Pt; L = phosphines or triphenylarsines) to give metallocyclobutane derivatives, which undergo exchange reactions of the neutral ligand L. The structures of these products have been assigned on the basis of the IR and NMR spectra. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
