Hydrogenolysis of tertiary phosphines coordinated on transition metals by hydrogen transfer from amines |
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| Authors: | Takeshi Nishiguchi Kazuo Fukuzumi |
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| Institution: | Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya Japan |
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| Abstract: | Considerable amounts of benzene were formed by heating triphenylphosphine complexes of transition metals in several types of organic compounds, especially in amines; in the case of a tributylphosphine complex, n-butane was detected. In the reactions with indoline, tetrahydroquinoline or dioxane, the hydrogen consumed for the hydrogenolysis was proved to arise from the amines or the ether. |
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| Keywords: | Author to whom correspondence should be addressed |
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