Syntheses of N-silylformamidines by the hydrosilylation of carbodiimides |
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| Authors: | Iwao Ojima Shin-Ichi Inaba Yoichiro Nagai |
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| Institution: | Sagami Chemical Research Center, 4-4-1 Nishi-Onuma, Sagamihara 229 Japan;Department of Chemistry, Gunma University, Kiryu, Gunma 376 Japan |
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| Abstract: | The hydrosilylation of carbodiimides was found to proceed at higher temperatures in the presence of catalytic amounts of palladium chloride or tris-(triphenylphosphine)chlororhodium to afford N-silylformamidines in high yield. These were found to be good precursors to formamidines and N-acetyl-formamidines. |
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| Keywords: | Author to whom correspondence should be addressed |
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