η-Allylpentacarbonylvanadium |
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| Authors: | M Schneider E Weiss |
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| Institution: | Institut für Anorganische und Angewandte Chemie der Universität Hamburg, Papendamm 6, D2 Hamburg 13 Bundesrepublik Deutschland |
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| Abstract: | The preparation of η-C3H5V(CO)5 from allyl chloride and sodium hexacarbonylvanadate (–I) is reported. Composition, IR and NMR spectra are in accordance with a π-bonded C3H5-moiety; the preparation has been extended to give complexes with substituted allyl groups. Furthermore (1-3-η-2-butenyl)pentacarbonylvanadium can be obtained by the addition of butadiene to HV (CO)6. |
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| Keywords: | Author to whom correspondence should be addressed |
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