Polysilane derivatives of the transition metals III. Preparations and spectra of manganese and iron derivatives |
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| Authors: | Brian K. Nicholson James Simpson |
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| Affiliation: | Department of Chemistry, University of Otago, P.O. Box 56, Dunedin New Zealand |
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| Abstract: | The preparations of derivatives of Mn(CO)5, Mn(CO)4PPh3 and π-Cp(CO)2Fe containing the polysilyl ligands (Me3Si)nMe3?nSi— (n = 1–3) are presented. The infrared and proton NMR spectra of the compounds are given and for the Mn(CO)5 derivatives, force constants are derived and discussed in terms of the σ-donor/π-acceptor properties of the silyl ligands. |
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| Keywords: | To whom correspondence should be addressed. |
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