Some cationic carbonyl complexes of rhodium(I) |
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Authors: | G.K.N. Reddy B.R. Ramesh |
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Affiliation: | Department of Chemistry, Bangnalore University, Bangalore - 560001 India |
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Abstract: | A number of cationic rhodium(I) complexes of the type [Rh(CO)2(NN)]ClO4, [Rh(CO)2L3]ClO4 and [Rh(CO)(NN)L2]ClO4, where (NN) is 2,2′-bipyridine or 1,10-phenanthroline and L is a tertiary phosphine or arsine, have been isolated and their structures assigned. The configuration of the complexes ion [Rh(CO)2L3]+ appears to depend critically on the size of the ligand L. |
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