Carbene complexes : IV. Far infrared and 31P NMR spectra of palladium and platinum carbene complexes |
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| Authors: | DJ Cardin B Çetinkaya MF Lappert |
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| Institution: | School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ Great Britain |
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| Abstract: | Infrared bands mainly associated with v(M—X2) stretching modes (M = Pd or Pt, and X = Cl, Br, or P) have been identified in the spectra of 35 carbene complexes. Based on these results and on |1J| (31 P—195 Pt) the trans-influence of the carbene ligands is assessed. |
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