Reactions of diethylcarbamoyl-lithium and bis(diethylcarbamoyl)mercury with highly fluorinated substrates |
| |
Authors: | J. Burdon P. Dodman |
| |
Affiliation: | Deparment of Chemistry, The University, P.O. Box 363, Birmingham B15 2TT Gt. Britain |
| |
Abstract: | Nucleophilic acylations have been carried out using a species reacting as diethylcarbamoyl-lithium. With pentafluorobenzaldehyde it gave the addition product, N,N-diethylpentafluoromandelamide, and with hexafluorobenzene, octafluorotoluene, decafluorocyclohexene and pentadecafluoro-octanoyl chloride it gave products which are formed by the nucleophilic replacement of fluorine or chlorine by the -CONEt2 group, though in poor yield. Reaction of bis(diethylcarbamoyl)mercury with decafluorocyclohexene, pentafluorobenzyl chloride and pentadecafluoro-octanoyl chloride afforded aminated products in low yields. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|