The reactivity of methylnickel, -palladium and -platinum compounds towards alkenes and alkynes |
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Authors: | N. Chaudhury M.G. Kekre R.J. Puddephatt |
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Affiliation: | Donnan Laboratories, The University of Liverpool, Liverpool L69 3BX Great Britain |
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Abstract: | The reactivity of alkyl-transition metals towards alkenes and alkynes falls in the sequence Et2Ni(bipy) > Et2Pt(bipy) > Me2Pt(bipy) > MePtCl(bipy) > MePdCl(bipy), which is also the order of decreasing energy of the filled metal d-orbitals. |
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Keywords: | To whom correspondence should be addressed. |
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