The reactivity of methylnickel, -palladium and -platinum compounds towards alkenes and alkynes |
| |
| Authors: | N Chaudhury MG Kekre RJ Puddephatt |
| |
| Institution: | Donnan Laboratories, The University of Liverpool, Liverpool L69 3BX Great Britain |
| |
| Abstract: | The reactivity of alkyl-transition metals towards alkenes and alkynes falls in the sequence Et2Ni(bipy) > Et2Pt(bipy) > Me2Pt(bipy) > MePtCl(bipy) > MePdCl(bipy), which is also the order of decreasing energy of the filled metal d-orbitals. |
| |
| Keywords: | To whom correspondence should be addressed |
| 本文献已被 ScienceDirect 等数据库收录！ |
