Aromatic Complexes of silver(I) triflate |
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Authors: | Martin B Dines |
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Institution: | Esso Research and Engineering Company, Linden, New Jersey 07036 U.S.A. |
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Abstract: | The silver salt of trifluoromethanesulfonic acid (silver(I) triflate) forms complexes with aromatics whose solid state stoichiometries involve two salt units per organic, as does the copper analog. Both show a similar preference for p-xylene among the eight carbon aromatic isomers, indicative of isomorphic structures. The two Ib systems are contrasted in their behavior as slurries with aromatics. |
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