Complexes dinucleaires pontes des metaux d8: II.preparation de deux series de composes du rhodium(I) pentacoordonne |
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Authors: | Andre Maisonnat Philippe Kalck Rene Poilblanc |
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Affiliation: | Groupe d''Etude et d''Application des complexes métalliques, Laboratoire de Chimie de Coordination du C.N.R.S., 31030 Toulouse Cedex France |
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Abstract: | In the course of the study of the reactivity of the dinuclear complexes [RhCl(CO)(C2H2)]2 and [RhSR(CO)2]2 towards nucleophiles, two series of dinuclear pentacoordinated rhodium(I) complexes, [RhCl(CO)(C2H4)(amine)]2 and [RhSR(CO)2PR3]2, have been isolated. |
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