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Oxidation of the [Rh(CO)2Cl2] anion in aqueous solution |
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| Authors: | YuS Varshavsky TG Cherkasova NA Buzina |
| Institution: | S.V. Lebedev Synthetic Rubber Research Institute, Leningrad U.S.S.R. |
| Abstract: | The reaction of rhodium(I) carbonyl chloride, Rh(CO)2Cl]2, with dichromate, cerium(IV) sulfate, hexachloroplatinic acid or p-benzoquinone in aqueous hydrochloric acid proceeds by consumption of 4 equivalents of oxidizing agent per mole or rhodium(I) in accordance with the equation RhI(CO)2 4e + H2O → RhIII(CO) + 2H+ + CO2A “cyclic” oxidation mechanism is suggested. |
| Keywords: | For correspondence |
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