Darstellung und eigenschaften von diorganogermaniumdisulfinsäureestern |
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| Authors: | Ekkehard Lindner Konrad Schardt |
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| Affiliation: | Lehrstuhl für Anorganische Chemie II der Universität, D74 Tübingen 1, Auf der Morgenstelle Deutschland |
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| Abstract: | Diorganogermaniumdisulfinic esters of the type R2Ge(O2SR′)2 (R = CH3, R′ = CH3, C6H5, p-CH3C6H4; R = C6H5, R′ = CH3, p-CH3C6H4) which are sensitive to hydrolysis are obtained by reaction of the corresponding diorganogermanium dichlorides with anhydrous silver sulfinates. The newly prepared compounds are thoroughly investigated on the basis of their 1H NMR, mass, IR and Raman spectra. The methyl ester (CH3)2Ge(O2SCH3)2 is compared with the already known sulfinato complex of tin with the same formal composition. |
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