Nickel-catalyzed synthesis of phosphonium salts |
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Authors: | L. Cassar M. Foà |
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Affiliation: | Centro Ricerche di Chimica Orgnaica, Montedison, Novara Italy |
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Abstract: | The nickel-catalyzed synthesis of phosphonium salts from aryl halides and triphenylphosphine is reported.The formation of phosphonium salts occurs by the oxidative addition reaction of Ni[P(C6H5)3]3 on the aryl halides and reaction of the coordinated aryl groups with triphenylphosphine.The influence of substituents on the aromatic nucleus is studied. |
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