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Nickel-catalyzed synthesis of phosphonium salts
Authors:L. Cassar  M. Foà
Affiliation:Centro Ricerche di Chimica Orgnaica, Montedison, Novara Italy
Abstract:The nickel-catalyzed synthesis of phosphonium salts from aryl halides and triphenylphosphine is reported.The formation of phosphonium salts occurs by the oxidative addition reaction of Ni[P(C6H5)3]3 on the aryl halides and reaction of the coordinated aryl groups with triphenylphosphine.The influence of substituents on the aromatic nucleus is studied.
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