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In situ study of the Porticello Bronzes by portable X-ray fluorescence and laser-induced breakdown spectroscopy
Authors:M Ferretti  G Cristoforetti  S Legnaioli  V Palleschi  A Salvetti  E Tognoni  E Console  P Palaia
Institution:

aIstituto per le Tecnologie Applicate ai Beni Culturali, Via Salaria, km 29.300, c.p.10, 00016 Monterotondo St. — Roma, Italy

bApplied Laser Spectroscopy Laboratory, Istituto per i Processi Chimico Fisici del CNR, Area di Ricerca di Pisa, Via G.Moruzzi, 1-56124 Pisa, Italy

cT.E.A. s.a.s., Via Luigi Pascali, 23/25-88100 Catanzaro, Italy

Abstract:This paper reports the results of a measurement campaign performed at the National Museum of Magna Grecia in Reggio Calabria (Italy). Portable X-Ray Fluorescence (XRF) and Laser-Induced Breakdown Spectroscopy (LIBS) instrumentation allowed in situ analysis of several bronze pieces belonging to the group of the so-called Porticello Bronzes. The find occurred at sea, off the village of Porticello (Reggio Calabria) in 1969 and consists of a number of fragments, including a bearded head, pertaining to at least two statues. The use of X-Ray Fluorescence and Laser-Induced Breakdown Spectroscopy techniques allowed for a classification of the fragments according to their elemental composition. The fragments appear to belong to at least two different statues; although, in general, the compositional classification agrees well with the stylistic analysis of the fragments, significant improvements with respect to previous achievements emerge from the joint results of the two techniques used.
Keywords:Archaeological bronze statues  Elemental analysis  XRF  LIBS  Cultural heritage
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