ESR study of nitro-substituted iminoxyl radicals |
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| Authors: | A V Il'yasov V I Morozov A A Vafina V A Naumov |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center, Academy of Sciences of the USSR, USSR |
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| Abstract: | Iminoxyl radicals involved in the homolytic oxidation of nitrolic acids, with the general formula (NO2)RC=NO., have been detected by means of ESR. In the presence of a strong acid, the ESR spectra of the radical (NO2)2C=NO. exhibits alternation of the line widths, owing to syn-anti isomerization.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1513–1516, July, 1991. |
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