Room-temperature Ni0-catalyzed cross-coupling reactions of aryl arenesulfonates with arylboronic acids |
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Authors: | Tang Zhen-Yu Hu Qiao-Sheng |
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Affiliation: | Department of Chemistry, College of Staten Island and the Graduate Center of the City University of New York, Staten Island, New York 10314, USA. |
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Abstract: | Room-temperature Ni(0)-catalyzed cross-coupling reactions of aryl arenesulfonates with arylboronic acids are described. The Ni(0) catalyst, derived from Ni(COD)2 and PCy3, proved to be a general one for the Suzuki-Miyaura cross-coupling of a variety of aryl arenesulfonates. The mild reaction condition, the readily availability of the catalyst, and excellent coupling yields make aryl arenesulfonates potentially useful substrates in organic synthesis. |
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