Ti-exchanged ZSM-5 as heterogeneous catalyst for allylation of aldehydes with allyltributylstannane |
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Authors: | Balin Kumar BhuyanArun Jyoti Borah Kula Kamal SenapatiProdeep Phukan |
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Institution: | Department of Chemistry, Gauhati University, Guwahati 781014, Assam, India |
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Abstract: | Titanium exchanged ZSM-5 catalyst has been prepared by treating an aqueous solution of titanium (IV) chloride with ZSM-5. The supported catalyst has been explored as effective and reusable catalyst for allylation reaction of aldehydes with allyltributylstannane. The new catalytic system promotes efficiently the allylation reaction in toluene condition to produce homoallylic alcohols in high yield. |
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Keywords: | ZSM-5 Heterogeneous catalyst Allylation Allyltributylstannane Homoallylic alcohol |
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