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Ti-exchanged ZSM-5 as heterogeneous catalyst for allylation of aldehydes with allyltributylstannane
Authors:Balin Kumar BhuyanArun Jyoti Borah  Kula Kamal SenapatiProdeep Phukan
Institution:Department of Chemistry, Gauhati University, Guwahati 781014, Assam, India
Abstract:Titanium exchanged ZSM-5 catalyst has been prepared by treating an aqueous solution of titanium (IV) chloride with ZSM-5. The supported catalyst has been explored as effective and reusable catalyst for allylation reaction of aldehydes with allyltributylstannane. The new catalytic system promotes efficiently the allylation reaction in toluene condition to produce homoallylic alcohols in high yield.
Keywords:ZSM-5  Heterogeneous catalyst  Allylation  Allyltributylstannane  Homoallylic alcohol
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