A novel 2D layer structure constructed from sandwich-type transition metal substituted tungstates and nickel coordination fragments: {[Ni(enMe)2]2[Ni(enMe)2(H2O)]2[As2W18Ni4(enMe)2O68]}·2H3O·2H2O |
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| Authors: | Zhi-Hui Yi Xiao-Bing Cui Xiao Zhang Ji-Qing Xu Guang-Di Yang Yan Chen Tie-Gang Wang Xiao-Yang Yu |
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| Institution: | aCollege of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023, China |
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| Abstract: | A novel polyoxometalate {Ni(enMe)2]2Ni(enMe)2(H2O)]2As2W18Ni4(enMe)2O68]}·2H3O·2H2O (1) (enMe = 1,2-propylenediamine) has been synthesized and characterized, which is the first high-dimensional structure constructed from sandwich-type transition metal substituted tungstates and transition metal coordination groups. |
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| Keywords: | Polyoxometalate Hydrothermal synthesis Crystal structure Sandwich-type cluster |
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