| HYDROLYTIC CLEAVAGE OF ACMET-GLY PROMOTED BY CIS-[Pd(MET)(D_2O)_2](NO_3)_2 |
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| 作者姓名： | Xiao Hua CHEN Long Gen ZHU N.M.Kostic |
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| 作者单位： | Xiao Hua CHEN; Long Gen ZHU;N.M.Kostic (Coordination Chemistry Institute，State Key Lab of Coordination Chemistry，Nanjing University，Nanjing 210093)(Department of Chemistry，lowa State University，Ames IA 50011，USA) |
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| 摘 要： | ＨＹＤＲＯＬＹＴＩＣＣＬＥＡＶＡＧＥＯＦＡＣＭＥＴ－ＧＬＹＰＲＯＭＯＴＥＤＢＹＣＩＳ－［Ｐｄ（ＭＥＴ）（Ｄ２Ｏ）２］（ＮＯ３）２￥ＸｉａｏＨｕａＣＨＥＮ；ＬｏｎｇＧｅｎＺＨＵ；Ｎ．Ｍ．Ｋｏｓｔｉｃ（ＣｏｏｒｄｉｎａｔｉｏｎＣｈｅｍｉｓｔｒｙＩｎｓｔｉ...
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| 关 键 词： | 埃阿 |
HYDROLYTIC CLEAVAGE OF ACMET-GLY PROMOTED BY CIS-[Pd(MET)(D_2O)_2](NO_3)_2 |
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| Xiao Hua CHEN, Long Gen ZHU,N.M.Kostic.HYDROLYTIC CLEAVAGE OF ACMET-GLY PROMOTED BY CIS-[Pd(MET)(D_2O)_2](NO_3)_2[J].Chinese Chemical Letters,1996(2). |
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| Authors: | Xiao Hua CHEN Long Gen ZHU NMKostic |
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| Abstract: | cis-Pd(met)(D2O)2]2 promoted hydrolysis of AcMet-Gly was monitored by H NMR spectroscopy. The observed rate constants, Kobs, strongly depend on the mole ratio of cis-Pd(met)(D2O)2]2 to AcMet-Gly.At least,one aqua ligand for each Pd(II)is necessary for fast hydrolysis reaction observed. Two aqua ligands of each Pd(II) make the reaction faster. |
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