Michael-type addition of secondary phosphine oxides to (1,4-cyclohexadien-3-yl)phosphine oxides |
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| Authors: | Stankevič Marek Jaklińska Magdalena Pietrusiewicz K Michał |
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| Institution: | Department of Organic Chemistry, Faculty of Chemistry, Marie Curie-Sk?odowska University, Gliniana 33, 20-614 Lublin, Poland. marek.stankevic@poczta.umcs.lublin.pl |
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| Abstract: | Base-induced reaction between (1,4-cyclohexadien-3-yl)phosphine oxides and secondary phosphine oxides gives 3,4-bis(phosphinoyl)cyclohexenes and 2,3-bis(phosphinoyl)cyclohexenes through an in situ isomerization of one of the cyclohexadienyl double bonds and a subsequent Michael-type addition of the secondary phosphine oxide. |
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