Synthesis and oxidative cleavage of poly(trimethylene diselenides) |
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| Authors: | N. V. Russavskaya E. P. Levanova E. N. Sukhomazova V. A. Grabel’nykh L. V. Klyba E. R. Zhanchipova A. I. Albanov N. A. Korchervin |
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| Affiliation: | (1) Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia |
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| Abstract: | 1-Bromo-3-chloropropane and elemental selenium react in hydrazine hydrate-alkali and hydrazine hydrate-amine systems to form poly(trimethylene diselenides). The reductive cleavage of the resulting selenokols yielded 1,3-propanediselenol, 1,2-diselenolane, and bis(alkylseleno)propanes. These compounds are important reagents for organic synthesis and ligands for complex formation. The products obtained were studided by GC-MS. |
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