| TCNQ脂类衍生物及其铜复合物的合成与红外光谱研究 |
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| 引用本文： | 黄伍桥,吴谊群,顾冬红,干福熹.TCNQ脂类衍生物及其铜复合物的合成与红外光谱研究[J].光谱学与光谱分析,2005,25(10):1577-1580. |
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| 作者姓名： | 黄伍桥 吴谊群 顾冬红 干福熹 |
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| 作者单位： | 1. 中国科学院上海光学精密机械研究所高密度光存储实验室，上海 201800
2. 黑龙江大学功能材料研究所，黑龙江 哈尔滨 150001 |
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| 基金项目： | 上海市科技发展基金（012261068）和国家自然科学基金（60207005）资助项目 |
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| 摘 要： | 首次合成了7，7，8，8-四氰基对苯醌二甲烷的脂类衍生物: TCNQ(C2H4COOR)2(R=CH3, C2H5, C3H7)及其铜电子转移复合物。通过元素分析确定这些化合物的组成, 对这些化合成物在4 000～400 cm-1范围内的主要红外光谱吸收峰进行了归属，并讨论了取代基对TCNQ类衍生物红外光谱的影响及其规律。
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| 关 键 词： | TCNQ脂类衍生物 电子转移复合物 红外光谱 |
| 文章编号： | 1000-0593（2005）10-1577-04 |
| 收稿时间： | 2003-07-16 |
| 修稿时间： | 2003-11-26 |
Ester Derivatives of Tetracyanoquinodimethane and Their CT Complexes:Synthesis and Studies by Infrared Spectroscopy |
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| HUANG Wu-qiao,WU Yi-qun,GU Dong-hong,GAN Fu-xi.Ester Derivatives of Tetracyanoquinodimethane and Their CT Complexes:Synthesis and Studies by Infrared Spectroscopy[J].Spectroscopy and Spectral Analysis,2005,25(10):1577-1580. |
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| Authors: | HUANG Wu-qiao WU Yi-qun GU Dong-hong GAN Fu-xi |
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| Institution: | 1. Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China2. Labs of Functional Materials, Heilongjiang University, Harbin 150080, China |
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| Abstract: | Three ester derivatives of tetracyanoquinodimethane and their CT complexes were synthesized and characterized by elementary analysis and infrared spectra. The principal infrared absorption peaks were assigned and discussed for the region of 4 000-400 cm^-1. Principal factors affecting principal infrared absorption were analyzed. |
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| Keywords: | Ester derivatives of TCNQ Charge-transfer complex IR spectrum |
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