Neutral copper-phosphido-borane complexes: synthesis, characterization, and use as precatalysts in C(sp)-P bond formation |
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| Authors: | Abdellah Ibrahim Bernoud Elise Lohier Jean-François Alayrac Carole Toupet Loïc Lepetit Christine Gaumont Annie-Claude |
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| Institution: | Laboratoire de Chimie Moléculaire et Thio-organique, UMR CNRS 6507, INC3M, FR 3038, ENSICAEN & Université de Caen, 6 boulevard du Maréchal Juin, F-14050 Caen, France. |
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| Abstract: | Copper-phosphido-borane complexes were synthesized and isolated for the first time. Their structures were experimentally and computationally investigated. They were shown to display catalytic activity in C(sp)-P bond formation. |
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