Air-stable, highly fluorescent primary phosphanes |
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| Authors: | Davies Laura H Stewart Beverly Harrington Ross W Clegg William Higham Lee J |
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| Institution: | School of Chemistry, Newcastle University, Newcastle upon Tyne, UK. |
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| Abstract: | Light without fright: a synthetic route to fluorescent primary phosphanes (RPH(2)) that are resistant to air oxidation both in the solid state and in chloroform solution is described. These versatile precursors undergo hydrophosphination to give tripodal ligands and subsequently fluorescent transition-metal complexes. |
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| Keywords: | fluorescence phosphanes rhenium synthetic methods |
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