Stannylplumbylenes: bonding between tetravalent tin and divalent lead |
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| Authors: | Drost Christian Lönnecke Peter Sieler Joachim |
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| Institution: | Universit?t Leipzig, Institut für Anorganische Chemie, Johannisallee 29, 04103 Leipzig, Germany. cdrost@uni-leipzig.de |
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| Abstract: | Depending on stoichiometry, reactions of the mixed valence Sn(0)/Sn(III) compound Sn(SnAr(3))(2) (1) (Ar = C(6)H(4)(O(i)Pr)(2)-2,6) with the likewise substituted plumbylene PbAr(2) (3) afforded either the homoleptic distannylplumbylene Pb(SnAr(3))(2) (4) or the heteroleptic arylstannylplumbylene Pb(Ar)SnAr(3) (5), a valence isomer of a stannaplumbene. |
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