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"Beta-cis-SAr effect" on decarbonylation from alpha,beta-unsaturated acyl and aroyl complexes |
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| Authors: | Kato Tomohiro Kuniyasu Hitoshi Kajiura Takamichi Minami Yasunori Ohtaka Atsushi Kinomoto Masanori Terao Jun Kurosawa Hideo Kambe Nobuaki |
| Institution: | Department of Applied Chemistry & Frontier Research Center, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka Suita, Osaka, 565-0871, Japan. |
| Abstract: | Lone pair of heteroatom located at the beta-cis position in alpha,beta-unsaturated acyl and aroyl group 10 metal complexes dramatically facilitated the stoichiometric and catalytic decarbonylation reactions. |
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