Binding of an acetonitrile molecule inside the ethereal cavity of a hexaarylbenzene-based receptor via a synergy of C-H...O/C-H...pi interactions |
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| Authors: | Shukla Ruchi Lindeman Sergey V Rathore Rajendra |
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| Institution: | Department of Chemistry, Marquette University, PO Box 1181, Milwaukee, WI 53201-1881, USA. |
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| Abstract: | A pair of hexaarylbenzene-based receptors, which contain a circular, as well as a partially-broken, ethereal fence around the central benzene ring, bind acetonitrile molecules via a synergy of C-H...O and C-H...pi interactions, as probed by X-ray crystallography. |
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