N-(2-Thenyl)derivatives of aminoalkyltriethoxysilanes,-silatranes and 2,2-dimethyl-1,3-dioxa-6-aza-silacyclooctane |
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Authors: | M. G. Voronkov N. F. Lazareva G. G. Efremova V. P. Baryshok |
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Affiliation: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033 Irkutsk, Russian Federation |
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Abstract: | The reactions of aminoalkylethoxysilanes and 2,2-dimethyl-1,3-dioxa-6-aza-2-silacyclooctane with 2-(chlormethyl)thiophene and its 5-chloroderivative lead to the correspondingN-(2-thenyl) derivatives. TheN-methyl-N-(2-thenyl)aminomethyltriethoxysilane and 5-chlorothyenyl derivative formed are converted by triethanolamine into silatranes.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 384–386, February, 1995. |
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Keywords: | aminoalkylethoxysilanes 2-(chlormethyl)thiophene 2-(chlormethyl)5-chlorothiophene N-methyl-N-(2-thenyl)-aminomethyltriethoxysilanes N-methyl-N-(2-thenyl)aminomethylsilatrane 2,2-dimethyl-1,3-dioxa-6-aza-2-silacyclooctane |
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